Bis[2-(butyliminomethyl)-4-chlorophenolato]iron(II)
نویسندگان
چکیده
In the title compound, [Fe(C(11)H(13)ClNO)(2)], the Fe(II) atom is four-coordinated in a square-planar geometry by the O and N atoms of two 2-(butyl-imino-meth-yl)-4-chloro-phenolate Schiff base ligands.
منابع مشابه
Bis[μ-2-(benzyliminomethyl)-4-chlorophenolato]bis[chloridocopper(II)]
The title complex, [Cu(2)(C(14)H(11)ClNO)(2)Cl(2)], has a centrosymmetric dinuclear structure where two symmetry-related copper(II) metal centres are bridged by the O atoms of two phen-oxy groups. Each copper(II) centre displays a distorted tetra-hedral coordination provided by one N atom and two O atoms from two Schiff base ligands and by one Cl atom. The Cu⋯Cu separation is 3.0702 (9) Å.
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In the title dinuclear complex, [Cu(2)(C(14)H(20)ClN(4)O)ClO]·3H(2)O, one Cu(II) cation assumes a distorted square-planar coordination geometry and the other a distorted square-pyramidal coordination geometry. Both Cu(II) cations are N,N',O-chelated by one arm of the 2,6-bis-[(2-amino-eth-yl)imino-meth-yl]-4-chloro-phenolate anion, and one oxide anion bridges the two Cu(II) cations, forming a d...
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The Schiff base ligand in the title compound, [Sn(C(4)H(9))(2)(C(11)H(12)ClNO(4))], chelates to the Sn atom through the two deprotonated O atoms, as well as through the N atom, to confer an overall cis-C(2)SnNO(2) trigonal-bipyramidal geometry at tin [C-Sn-C = 130.3 (1)°]. The hydr-oxy groups engage in O-H⋯O hydrogen bonding with the O atoms of adjacent mol-ecules, generating a chain running al...
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